Elastocaloric Heat Pump by Twist Induced Periodical Non-Linear Stress for Low Hysteresis and High Carnot Efficiency
By
Xiao, YC (Xiao, Yicheng) [1] ; Mei, GK (Mei, Guangkai) [1] ; Feng, DY (Feng, Danyang) [1] , [2] ; Zhao, WB (Zhao, Wubin) [1] ; Guo, WJ (Guo, Wenjin) [1] ; Leng, XQ (Leng, Xueqi) [1] ; Qian, D (Qian, Dong) [3] ; Zhao, WQ (Zhao, Weiqiang) [1] ; Bai, J (Bai, Jie) [4] ; Wang, ZQ (Wang, Zongqian) [5] ; Zhu, MF (Zhu, Meifang) [6] ; Zhou, X (Zhou, Xiang) [2] , [4] ; Liu, ZF (Liu, Zunfeng) [1]
DOI
10.1002/adma.202407009
Early Access
SEP 2024
Indexed
2024-10-01
Document Type
Article; Early Access
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Abstract
Elastocaloric cooling is one of the most promising solid-state cooling approaches to address the issues of energy shortage and global warming. However, the cooling efficiency and cycle life of this technology need to be improved, and the required driving force shall be reduced. Here, a novel elastocaloric heat pump by periodic non-linear stress is developed by employing fiber twisting and separated cooling and heating media. The non-linear stress generated by fiber twisting yields a hierarchical, rigid-yet-flexible architecture and a periodic entropy spatial distribution, which result in a low mechanical hysteresis work and a high cooling efficiency (a maximum material coefficient of performance (COP) of 30.8 and a maximum Carnot efficiency of 82%). The torsional non-linear stress inhibits crack propagation and results in a highly extended cycle life (14752 cycles, more than ten times of fiber stretching). The heat pump exhibits a maximum average temperature span of 25.6 K, a maximum specific cooling power of 1850 W Kg-1, a maximum device COP of 19.5, and a maximum device power of 5.0 W, under each optimal condition.
Fiber twisting induces periodic non-linear stress, leading to high elastocaloric performance and material COP. A novel elastocaloric heat pump is designed using this technique, incorporating a three-port valve and a pump to separate the cooling and heating media, which results in low hysteresis, high efficiency, enhanced durability, and excellent cooling.