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刘永胜课题组 | NANO-MICRO LETTERS

发布人:    发布时间:2023/08/07   浏览次数:

Recent Progress of Layered Perovskite Solar Cells Incorporating Aromatic Spacers


作者

Gao, YP (Gao, Yuping) [1] , [2] ; Dong, XY (Dong, Xiyue) [1] , [2] ; Liu, YS (Liu, Yongsheng) [1] , [2] , [3]

Journal

NANO-MICRO LETTERS

15

1

DOI

10.1007/s40820-023-01141-2

文献号

169

出版时间

DEC 2023

已索引

2023-08-01

文献类型

Review

摘要

Layered two dimensional (2D) or quasi-2D perovskites are emerging photovoltaic materials due to their superior environment and structure stability in comparison with their 3D counterparts. The typical 2D perovskites can be obtained by cutting 3D perovskites along < 100 > orientation by incorporation of bulky organic spacers, which play a key role in the performance of 2D perovskite solar cells (PSCs). Compared with aliphatic spacers, aromatic spacers with high dielectric constant have the potential to decrease the dielectric and quantum confinement effect of 2D perovskites, promote efficient charge transport and reduce the exciton binding energy, all of which are beneficial for the photovoltaic performance of 2D PSCs. In this review, we aim to provide useful guidelines for the design of aromatic spacers for 2D perovskites. We systematically reviewed the recent progress of aromatic spacers used in 2D PSCs. Finally, we propose the possible design strategies for aromatic spacers that may lead to more efficient and stable 2D PSCs.