hermoresponsive Polymers Based on Tertiary Amine Moieties

Pang, B (Pang, Bo) 1Yu, YW (Yu, Yuewen) 1Zhang, WQ (Zhang, Wangqing) 1

MACROMOLECULAR RAPID COMMUNICATIONS, 2021, Article Number 2100504

DOI 10.1002/marc.202100504

Abstract

Thermoresponsive polymers exhibiting unique reversible phase transition properties in aqueous solution in response to temperature stimuli have been extensively investigated. In the past two decades, thermoresponsive polymers based on tertiary amine moieties have achieved considerable progress and become an important family of thermoresponsive polymers, including tertiary amine functionalized poly((meth)acrylamide)s, poly((meth)acrylate)s, poly(styrene)s, poly(vinyl alcohol)s, and poly(ethylene oxide)s, which exhibit lower critical solution temperature and/or upper critical solution temperature in water or aliphatic alcohols. Their phase transition behavior can be modulated by the solution pH and CO2 due to the protonation of tertiary amine moieties in acidic condition and deprotonation in alkaline condition and the charged ammonium bicarbonate formed by the tertiary amine moieties and CO2. The aim of this review is to summarize the recent progress in the thermoresponsive polymers based on tertiary amine moieties.