A privileged ternary blend enabling non-fullerene organic photovoltaics with over 14% efficiency

Yan, J (Yan, Jing)^{[ 1,2,3 ]} ; Yi, YQQ (Yi, Yuan-Qiu-Qiang)^{[ 1,2,3 ]} ; Zhang, JQ (Zhang, Jianqi)^{[ 4 ]} ; Feng, HR (Feng, Huanran)^{[ 1,2,3 ]} ; Ma, YF (Ma, Yanfeng)^{[ 1,2,3 ]} ; Wan, XJ (Wan, Xiangjian)^{[ 1,2,3 ]} ; Li, CX (Li, Chenxi)^{[ 1,2,3 ]} ; Wei, ZX (Wei, Zhixiang)^{[ 4 ]} ; Chen, YS (Chen, Yongsheng)^{[ 1,2,3 ]}

JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8(43): 15135-15141

DOI: 10.1039/d0tc02778b

摘要

Two non-fullerene small molecule acceptors (NF-SMAs) NT-4F and NT-4Cl with halogenated end groups were designed and synthesized. When blended with PM6, the NT-4Cl-based binary device gave a power conversion efficiency (PCE) of 11.44% with a fill factor (FF) of 74.1% while the NT-4F binary system showed a PCE of 9.46%. To further broaden the absorption profile and fine-tune the morphology, NCBDT-4Cl, an acceptor with a similar chemical structure and identical molecular orientation to NT-4Cl, was selected as a combinatory component to the PM6:NT-4Cl system. As a result, the ternary device achieved a dramatically promoted PCE of 14.55% with a synergistically enhanced FF of 77.1% and a J(sc) of 20.99 mA cm(-2) as well as a decreased energy loss (E-loss) of 0.51 eV, which represents the best performance for NT-based NF-SMAs to date.